電導率與溫度具有很大相關性。金屬的電導率隨著溫度的升高而減小。半導體的電導率隨著溫度的升高而增加。在一段溫度值域內，電導率可以被近似為與溫度成正比。為了要比較物質在不同溫度狀況的電導率，必須設定一個共同的參考溫度。電導率與溫度的相關性，時常可以表達為，電導率對上溫度線圖的斜率。
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